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The hydration characteristics of the interlayer cations will determine 8289/frame/ch02 Page 38 Tuesday, August 15, 2000 9:12 PM 38 GEOENVIRONMENTAL ENGINEERING the hydrated basal spacing. This aspect of the montmorillonites will be discussed in greater detail in the next chapter when we deal with the phenomenon of swelling clays as part of the study of clay-water interactions. 9. As we can see, substitution of one ion for another in the clay lattice and imperfections at the surface (especially at the edges) occurring during crystallization or formation of the mineral results in the development of negative electric charges on the clay particles.
1997). , are clear examples of the need for environmental regulations designed to deal specifically with waste containment and management for the protection of public health and the environment. , leachates), must be below limiting concentrations of toxicants. Since water is the primary carrier for contaminants in the substrate, the barrier system which separates the waste material and/or waste leachates in a landfill from the natural substrate material and groundwater constitutes the technical element that can be controlled through the use of technical design/construction specifications and through regulatory requirements and specifications.
Because of the nature of the soil fractions, and because of the manner in which the soils are obtained or developed, it is possible to obtain particle and ped arrangements that favour a horizontal orientation. This gives rise to anisotropic behaviour of the soil, and is particularly important in considerations of transport processes in soils. The factors that need proper consideration include not only orientation of fabric elements, but also orientation of the macro- and micropores. 14 shows various modes of fabric orientation of both ped units and total REV elements.