By Robert E. Treybal
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Eng. Chem. 41, 2039 Olsen, A. , and E. R. Washburn: /. Am. Chem. Soc. 67, 303 (1935). Othmer, D. , and P. E. Tobias: Ind. Eng. Chem. 34, 690 (1942). 32. 33. 34. 35. 36. 37. , J. (1948). (1949). 38. , p. 693. and J. W. McBain: Ind. Eng. Chem. 38, 741 (1946). R. , and D. F. Wilcock: Trans. Am. Inst. Chem. Engrs. 37, 649 (1941). 41. Saal, N. , and W. J. D. Van Dijck: World Petroleum Congress, London, 1933, 39. Palit, S. , 40. Ruthruff, Proc. 2, 352. 42. Schreinemakers, F. A. 43. , 29, 586 (1899). 44.
17C. [Data and of Zawidzki, Z. Physik. Chem. 39, ABA PREDICTION OF DISTRIBUTION cient become more approaches x = erratic 47 and scatter badly as the solution concentration The activity coefficient is very sensitive to even small errors in measurement, and the experimental difficulties in making measurements on very dilute or highly concentrated solutions are considerable. 0. placed in a single value of activity coefficient for very dilute or very concentrated solutions. 0 and show other unusual The systems acetic acid-water, sodium chloride-water, and acetaldehyde-water are typical of these.
To titrate known mixtures curve. of C and B M N , N If analysis of all three components is difficult, it is usually possible to determine a physical property of mixtures along the binodal curve which will vary sufficiently with concentration so that it can be used for analytical purposes. Specific gravity, or refractive index, is frequently chosen, since these are simple to measure. Thus, determination of the specific gravity of the layers and and reference to a plot of specific gravity vs. per cent N N C and 0.