By G. Guelachvili, K. Narahari Rao (auth.), G. Guelachvili (eds.)
Volume II/20 presents severely evaluated info on loose molecules, bought from infrared spectroscopy and comparable experimental and theoretical investigations.
The quantity is split into 4 subvolumes, A: Diatomic Molecules, B: Linear Triatomic Molecules, C: Nonlinear Triatomic Molecules, D: Polyatomic Molecules.
The current subvolume II/20 B2° includes facts for 16O12C16O. Subvolume II/20 B2ß containing info for CO2 isotopomer and Subvolume B3 containing information for CS2 ... N3, and extra subvolumes are in preparation.
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Extra info for Linear Triatomic Molecules - OCO. Part a
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40) b;(T) = b$‘-o)(T’/‘T)“, where T,, is a standard reference temperature. 41) P’ = (l/b,)[(ln2)/~]1’2. 42) with b, is the Doppler halfwidth, defined as one half of the full width of the line measured at the points where the absorption coefficient k(v) = (l/2) k(v,). 581. 44) where k is the Boltzmann constant, N, is the Avogadro’s number, T is the temperature of the gas in K, c is the speed of light, and M is the molecular weight of the gas in amu. 45) I P’ is given above, see Eq. 46) 5 = [(v - vO)/b,](ln2)“2.
30) where ρa and ρ b are the densities of the absorbing and perturbing gases and l is the path length. The gas densities were expressed in amagats (see footnote on p. XXXI). 31) LII Introduction where N is the density of the gas, carbon dioxide in this case, and α is the absorption coefficient and T is the temperature. 32) where L is the path length and ν is in cm–1. 33) band where α 1 is the linear integrated absorption coefficient and represents the allowed band contribution and α 2 is the binary integrated absorption coefficient and represents the collision induced band contribution.
Therefore, each actual level is a mixture of the two. In the 1950s, Professor Gilbert Amat from the Faculté des Sciences de Paris, France, advocated that the labeling of the levels of carbon dioxide should reflect this fact and suggested that it is more appropriate to write them as (1000, 0200)I and (1000,0200)II . Since there is a similar resonance between certain higher levels of this molecule it was argued that the designations of all the energy levels of CO2 should be changed from their conventional υ1 , υ 2l , υ3 notations.