By Joseph D. Rosen
content material: Low-molecular-weight organosulfur compounds in nature / Eric Block --
Chemical mechanisms of the cytochrome P-450 monooxygenase-catalyzed metabolism of phosphorothionate triesters / R.A. Neal --
Sulfur in propesticide motion / T.R. Fukuto and M.A.H. Fahmy --
S-oxygenation in herbicide metabolism in mammals / D.H. Hutson --
Toxicological value of oxidation and rearrangement reactions of S-chloroallyl thio- and dithiocarbamate herbicides / Ingolf Schuphan ... [et al.] --
organic and chemical habit of perhalogenmethylmercapto fungicides / Ingolf Schuphan ... [et al.] --
Comparative metabolism of dithiolane pesticides in crops, animals, and the surroundings / Chia C. Ku and Inder P. Kapoor --
Roles of iron-sulfur proteins in degradation of pesticidal chemical compounds by means of microorganisms / Fumio Matsumura, okay. Yoneyama, and J. Marshall Clark --
Catabolism of glutathione conjugates of insecticides in better crops / G.L Lamoureux and D.G. Rusness --
position of intestine microflora in metabolism of glutathione conjugates of xenobiotics / J.E. Bakke ... [et al.].
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R. Pestic. Biochem. , 1976, 6, 1. 10. H. J. Εcon. , 1970, 63, 480. 11. R. J. Agr. , 1973, 21, 747. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1981. 3. FUKUTO AND FAHMY Sulfur in Propesticide Action 49 12. A. Pestic. Biochem. , 1973, 3, 435. 13. R. J. Agr. , 1979, 27, 261. 14. R. Pestic. Biochem. , 1979, 12, 55. 15. , So. Afr. Pat. , 1971. 16. S. Pat. 3,663,594, May 16, 1972. 17. S. Pat. 3,847,951, Nov. 21, 1974. 18. Farbenfab. Bayer AG, Belg. Pat. 772,634, March 1972. 19.
In c o n t r a s t , the rate of metabolism of benzphetamine (as determined by formaldehyde production) remained l i n e a r throughout the incubation p e r i o d . As with the data using i n t a c t microsomes (_19), these data suggest that the binding of some r e a c t i v e product of parathion to one or both of the enzymes of t h i s r e c o n s t i t u e d system i s respons i b l e f o r the departure of the rate of metabolism of parathion from linearity. The i n h i b i t i o n was not due to i n a c t i v a t i o n of NADPH since an excess of t h i s c o f a c t o r d i d not improve l i n e a r i t y .
A. Biochemistry, 1972, 11, 3224. W. J . Amer. Chem. , 1971, 93, 3304. R. Biochem. , 1976, 25, 2671. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1981. 34 SULFUR IN PESTICIDE ACTION AND METABOLISM 12. R. Pesticide Biochem. , 1978, 8, 158. 13. ; Miyamoto, Agr. Biol. , 1976, 40, 2125. 14. ; Mazzanti, G. J. Chem. Soc. (B), 1,971, 1547. 15. ; Zwanenburg, B. , 1966, 65. 16. P. J. Amer. Chem. , 1974, 96, 5005. 17. ; Durst, T. J. Amer. Chem. , 1963, 85, 2676. 18. A. Toxicol. Appl.